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Protecting groupSemipinacol rearrangementAsymmetric synthesisFunctional groupRearrangement reactionStereospecific catalystHeliceneSynthonChiral resolutionAsymmetric carbonTacticityStereocenterHomoconjugationConformational isomerismAtropisomerOrganic synthesisWalden inversionSquare planar molecular geometryDesymmetrizationCharge-transfer complexAbsolute configurationChloromethylationStructural isomerismHydroxymethylationDiastereoisomerChiralityStereospecificityNitrogen inversionCinchonidineStereocentreCycloisomerizationBioconjugationIsomerizationChemoselectivityCyanohydrinReactive intermediateEnantioselective synthesisStereoisomerismReaction intermediateTransition state analogRacemizationSpecific rotationFormylation reactionCyclopropanationChemical synthesisSubstituentReagentSigmatropic reactionCyclophaneAcetylationHydroxylationTransition stateEndo-exo isomerismEpimerizationStereoisomerAryl halideAxial chiralityStereochemistryTriphenylstibineCocrystalCyanamideSide chainTrans effectElectrocyclic reactionHybridizationTelechelic polymerMesomeric effectProchiralityAcyl halideHydroacylationDerivatizationCyclic compoundRetrosynthesisPericyclic reactionMonoamidePyrroloTotal synthesisOrganic compoundSemisynthesisGlycosyl donorStereospecific synthesisCarboxylationDichalcogenideCarbomerLigandCycloadditionAmplificationStructural isomerAllylic rearrangementCarbenoidTransition metal carbene complexThiosemicarbazonePolycondensationPhenylationCatecholboraneIsoxazolidineTautomerismNucleophilic aromatic substitutionPivaloyloxymethylSemisynthetic